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Advanced technologies for longer-lasting electric vehicles
- Date : 23-03-28
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- Carbon fiber paper is used instead of copper thin film to achieve long-term stability and high energy density for lithium metal batteries
Owing to the worldwide trend of utilizing electric vehicles, there has been a rise in demand for next-generation secondary batteries with higher capacity and faster charging than the lithium-ion batteries currently in use. Lithium metal batteries have been recognized as promising rechargeable batteries because lithium metal anode exhibits theoretical capacity 10 times higher than commercial graphite anode. During charging-discharging processes, however, lithium dendrites grow on the anode, leading to poor battery performance and short-circuit.
Dr. Sungho Lee, Head of the Carbon Composite Materials Research Center of the KIST Jeonbuk Institute of Advanced Composition Materials (President Dr. Seok-Jin Yoon, Director General Jin-Sang Kim) and Professor KwangSup Eom, the Gwangju Institute of Science and Technology (GIST, Acting President Rae-Gil Park), have developed a technology to improve the durability using carbon fiber paper as the anode material for lithium metal batteries.
The KIST-GIST joint research team replaced the lithium metal-coated copper thin film with a thin carbon fiber paper containing lithium metal. The developed carbon fiber paper possessed hierarchical structure on the carbon monofilament composed of amorphous carbon and inorganic nanoparticles, resulting in enhancing the lithium affinity and preventing the growth of lithium dendrite. Although copper thin film anode short-circuits after approximately 100 cycles, the developed carbon fiber paper anode exhibits excellent cycling stability for 300 cycles. Furthermore, lithium metal battery using developed carbon fiber paper shows a high energy density of 428 Wh/kg, which is approximately 1.8 times higher than that using copper thin film (240 Wh/kg). From a process point of view, another advantage is to simplify the electrode manufacturing process because the molten lithium is quickly infused into the carbon fiber paper.
Regarding the significance of this research, Dr. Sung-Ho Lee, Head of the Center at KIST, who led the research, said, "Considering the five times lower density and lower cost of carbon fiber compared to copper, our proposed anode material is an important achievement that can accelerate the commercialization of durable and lightweight lithium metal batteries."
KIST was established in 1966 as the first government-funded research institute in Korea. KIST now strives to solve national and social challenges and secure growth engines through leading and innovative research. For more information, please visit KIST’s website at https://eng.kist.re.kr/
This research was carried out as a KIST Institutional Program and a nanomaterial technology development project under the support of the Ministry of Science and ICT (Minister Lee Jong-ho). The results were published in the January issue of the international journal Advanced Energy Materials (IF=29.698, JCR top 2.464%).
Journal : Advanced Energy Materials
Title : Construction of Hierarchical Surface on Carbon Fiber Paper for Lithium Metal Batteries with Superior Stability
Publication Date : 15-Jan-2023
DOI : https://doi.org/10.1002/aenm.202203770